Peng Liyuan - dubbed the Chinese Kate Middleton - was attending the Lord Mayor's banquet as part of her husband Xi Jinping's historic state visit to the UK.
But when Madame Peng, who was a famous folk singer before she married President Xi , arrived at the lavish do at London's Guildhall, something seemed odd with her foundation.
The fashion-conscious first lady had unsightly white powder all over her forehead and nose.
Silica powder could be behind the gaffe.
The powder can help absorb oil and control shine - but if too much is applied it can really stand out in photographs.
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